Crude oil is separated into it's various hydrocarbons by fractional distillation, which happens like so:
1. Crude oil is heated
2. As a gas it floats upwards, where the temperature decreases
3. One by one, each compound in the crude oil will reach it's condensing point and condense
4. It will then be collected
This ensures that all groups with similar condensing temperatures (known as fractions) are each separated, since each fraction is a different substance
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